Lithium ion
accumulator batteries produce current by moving lithium ions. The
battery usually contains a cathode (positive electrode) made of a
mixed metal oxide, such as lithium cobalt oxide, and an anode
(negative electrode) made of graphite. While the battery is being
charged, lithium ions migrate into the anode, where they are stored
between the graphite layers. When the battery is being discharged,
these ions migrate back to the cathode.
It would be nice to
have an anodic material that could store more lithium ions than
graphite. Silicon presents an interesting alternative. The problem:
silicon expands a great deal while absorbing lithium ions
(charging) and shrinks when giving them up (discharging). After
several cycles the required thin silicon layers are pulverized and
can no longer be charged.
Cho’s team has now
developed a new method for the production of a porous silicon anode
that can withstand this strain. They annealed silicon dioxide
nanoparticles with silicon particles whose outermost silicon atoms
have short hydrocarbon chains attached to them at 900 °C under an
argon atmosphere. The silicon dioxide particles were removed from
the resulting mass by etching. What remained were carbon-coated
silicon crystals in a continuous, three-dimensional, highly porous
structure.